Adsorption and Colloids
Maharashtra Board · Class 11 · Chemistry
Quick revision notes for Adsorption and Colloids — Maharashtra Board Class 11 Chemistry. Key concepts, formulas, and definitions for last-minute revision.
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Key Topics to Revise
Adsorption Fundamentals
- Adsorption occurs due to unbalanced forces at surfaces of solids and liquids
- Molecules at surface have unsatisfied valencies leading to attraction of gas molecules
- London dispersion forces and van der Waals forces cause adsorption
Types of Adsorption
- Physical adsorption (physisorption): Weak van der Waals forces, low heat of adsorption (20-40 kJ/mol)
- Chemical adsorption (chemisorption): Chemical bonds, high heat of adsorption (40-200 kJ/mol)
- Physisorption: Non-specific, reversible, multilayer formation possible
Factors Affecting Adsorption
- Nature of adsorbate: Gases with high critical temperature (easily liquefiable) are readily adsorbed
- Nature of adsorbent: Porous materials with large surface area are good adsorbents
- Surface area: Adsorption increases with surface area - finely divided substances are better adsorbents
Adsorption Isotherms
- Adsorption isotherm shows relationship between amount adsorbed and pressure/concentration at constant temperature
- Freundlich isotherm: x/m = kP^(1/n) where n > 1
- Logarithmic form: log(x/m) = log k + (1/n)log P
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