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Alcohols, Phenols and Ethers

Maharashtra Board · Class 12 · Chemistry

Flashcards for Alcohols, Phenols and Ethers — Maharashtra Board Class 12 Chemistry. Quick Q&A cards covering key concepts, definitions, and formulas.

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Card 1Classification and Structure

Define alcohols and give their general formula. How are they classified based on the carbon atom to which -OH is attached?

Answer

Alcohols are organic compounds containing hydroxyl group (-OH) attached to a saturated carbon atom. General formula: R-OH Classification based on carbon: • Primary (1°): -OH attached to primary carbo

Card 2Classification and Structure

What is the difference between phenols and aromatic alcohols? Give examples.

Answer

Phenols: Hydroxyl group (-OH) directly attached to benzene ring carbon Example: C₆H₅-OH (phenol) Aromatic alcohols: Hydroxyl group (-OH) attached to side chain carbon of aromatic ring Example: C₆H₅-C

Card 3Nomenclature

Write IUPAC names for the following compounds: (a) CH₃-CH₂-CH₂-OH (b) (CH₃)₂CH-OH (c) C₆H₅-OH (d) CH₃-O-CH₂-CH₃

Answer

(a) Propan-1-ol (b) Propan-2-ol (c) Benzenol (or Phenol - both accepted) (d) Methoxyethane Naming rules: • Alcohols: Replace -e with -ol, number the position • Phenols: Benzenol or phenol • Ethers: A

Card 4Preparation of Alcohols

Describe the preparation of alcohols from alkenes by acid-catalyzed hydration. Include the mechanism and Markownikoff's rule.

Answer

Reaction: R-CH=CH₂ + H₂O → H₂SO₄/heat → R-CH(OH)-CH₃ Mechanism: Step 1: H₂SO₄ + alkene → carbocation (follows Markownikoff's rule) Step 2: H₂O attacks carbocation Step 3: Deprotonation gives alcohol

Card 5Preparation of Alcohols

What is hydroboration-oxidation? How does it differ from acid-catalyzed hydration of alkenes?

Answer

Hydroboration-oxidation: Step 1: R-CH=CH₂ + B₂H₆ → (R-CH₂-CH₂)₃B Step 2: (R-CH₂-CH₂)₃B + H₂O₂/OH⁻ → 3 R-CH₂-CH₂-OH Differences: • Anti-Markownikoff addition (OH goes to less substituted carbon) • No

Card 6Preparation of Alcohols

Explain the preparation of alcohols using Grignard reagents. What types of alcohols are formed from different carbonyl compounds?

Answer

Grignard Reaction: R-MgX + C=O → R-C-OMgX → H₃O⁺ → R-C-OH Products from different carbonyls: • Formaldehyde (HCHO) → Primary alcohol (1°) • Aldehyde (R'CHO) → Secondary alcohol (2°) • Ketone (R'COR''

Card 7Preparation of Phenols

Describe the industrial preparation of phenol from cumene (cumene-phenol process). Why is this method commercially important?

Answer

Cumene-Phenol Process: Step 1: C₆H₅-CH(CH₃)₂ + O₂ → C₆H₅-CH(OOH)-CH₃ (cumene hydroperoxide) Step 2: C₆H₅-CH(OOH)-CH₃ + H⁺ → C₆H₅-OH + (CH₃)₂CO Commercial importance: • Both phenol and acetone are val

Card 8Physical Properties

Why do alcohols and phenols have higher boiling points than corresponding alkanes? Explain with hydrogen bonding.

Answer

Higher boiling points due to hydrogen bonding: • -OH group forms intermolecular hydrogen bonds • H of one molecule attracts O of another molecule • Strong dipole-dipole interactions • More energy nee

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