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Alcohols, Phenols and Ethers

Madhya Pradesh Board · Class 12 · Chemistry

Flashcards for Alcohols, Phenols and Ethers — Madhya Pradesh Board Class 12 Chemistry. Quick Q&A cards covering key concepts, definitions, and formulas.

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A reaction scheme showing the hydroboration-oxidation of an alkene (e.g., propene) to form an alcohol, highlighting the anti-Markownikov addition.
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Card 1Classification of Alcohols

How do you classify alcohols based on the carbon atom to which -OH is attached?

Answer

Primary (1°): -OH attached to carbon with one alkyl group (R-CH₂-OH) Secondary (2°): -OH attached to carbon with two alkyl groups (R₂CH-OH) Tertiary (3°): -OH attached to carbon with three alkyl group

Card 2Preparation of Alcohols

Write the balanced equation for acid-catalyzed hydration of propene to form an alcohol.

Answer

CH₃-CH=CH₂ + H₂O → CH₃-CH(OH)-CH₃ Reaction follows Markovnikov's rule: H⁺ adds to carbon with more hydrogens, OH⁻ adds to carbon with fewer hydrogens. Mechanism: Formation of 2° carbocation → nucleoph

Card 3Chemical Properties of Phenols

Calculate the number of moles of NaOH required to completely neutralize 0.1 mol of phenol (C₆H₅OH).

Answer

Balanced equation: C₆H₅OH + NaOH → C₆H₅ONa + H₂O Molar ratio: 1:1 (phenol : NaOH) Given: moles of phenol = 0.1 mol Moles of NaOH required = 0.1 mol Mass of NaOH = 0.1 × 40 = 4.0 g Answer: 0.1 moles of

Card 4Acidity of Phenols

Why are phenols more acidic than alcohols? Explain with resonance structures.

Answer

Phenols are more acidic because the phenoxide ion (C₆H₅O⁻) is stabilized by resonance. Resonance structures show delocalization of negative charge over the benzene ring. In alcohols, alkoxide ion (RO⁻

Card 5Reactions of Alcohols

What products are formed when butan-2-ol reacts with concentrated H₂SO₄ at 170°C?

Answer

Dehydration reaction occurs: CH₃-CH(OH)-CH₂-CH₃ → CH₃-CH=CH-CH₃ + H₂O Major product: But-2-ene (follows Saytzeff's rule - most substituted alkene) Minor product: But-1-ene Mechanism: Protonation → car

Card 6Reactions of Alcohols

Calculate the volume of H₂ gas (at STP) produced when 2.3 g of ethanol reacts completely with sodium.

Answer

Balanced equation: 2C₂H₅OH + 2Na → 2C₂H₅ONa + H₂ Molar mass of ethanol = 46 g/mol Moles of ethanol = 2.3/46 = 0.05 mol From equation: 2 mol ethanol → 1 mol H₂ Moles of H₂ = 0.05/2 = 0.025 mol Volume a

Card 7Chemical Tests for Alcohols

Write the complete mechanism for the Lucas test reaction with tertiary alcohols.

Answer

Lucas reagent: Conc. HCl + ZnCl₂ For tertiary alcohol: (CH₃)₃COH + HCl → (CH₃)₃CCl + H₂O Mechanism: 1. Protonation: (CH₃)₃COH + H⁺ → (CH₃)₃COH₂⁺ 2. Carbocation formation: (CH₃)₃COH₂⁺ → (CH₃)₃C⁺ + H₂O

Card 8Nomenclature of Alcohols

Name the following compounds according to IUPAC nomenclature: (i) CH₃CH(OH)CH₂CH₃ (ii) (CH₃)₂CHCH₂OH

Answer

(i) CH₃CH(OH)CH₂CH₃: Longest chain: 4 carbons (butane) -OH on carbon 2 IUPAC name: Butan-2-ol (ii) (CH₃)₂CHCH₂OH: Longest chain: 3 carbons (propane) Branched methyl on carbon 2 -OH on carbon 1 IUPAC

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