Electrochemistry
Uttar Pradesh Board · Class 12 · Chemistry
Complete topic list for Electrochemistry in Uttar Pradesh Board Class 12 Chemistry. Key concepts, sub-topics, and what to focus on for board exams.
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Get startedTopics in Electrochemistry
Electrochemical Cells
- Electrochemical cells convert chemical energy to electrical energy (galvanic) or vice versa (electrolytic)
- Daniell cell: Zn(s) + Cu²⁺(aq) → Zn²⁺(aq) + Cu(s) produces 1.1V
- Anode: electrode where oxidation occurs (negative in galvanic cells)
Nernst Equation
- Relates cell potential to concentration of reactants and products
- Temperature dependence of cell potential
- For non-standard conditions, cell potential differs from standard potential
Gibbs Energy and Equilibrium Constant
- Spontaneous reactions have negative ΔG and positive E°cell
- Relationship between thermodynamics and electrochemistry
- Equilibrium constant can be calculated from standard cell potential
Conductance of Electrolytic Solutions
- Resistance (R) in ohms (Ω), Conductance (G) = 1/R in siemens (S)
- Resistivity (ρ) and conductivity (κ) are material properties
- Molar conductivity (Λm) accounts for concentration effects
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