Some Basic Principles and Techniques — Revision Notes
NEET-UG · Chemistry
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Key concepts, formulas, and definitions from Some Basic Principles and Techniques for NEET-UG Chemistry preparation.
Key Topics to Revise
Tetravalency and Hybridization of Carbon
- Carbon has 4 electrons in outer shell (1s² 2s² 2p²), making it tetravalent
- Ground state carbon is divalent, but promotion of 2s electron to 2p orbital makes it tetravalent
- Promotion requires 96 kcal/mol energy, which is regained during bond formation
IUPAC Nomenclature System
- IUPAC name = Prefix + Word root + Primary suffix + Secondary suffix
- Word root indicates number of carbon atoms (meth-, eth-, prop-, but-, etc.)
- Primary suffix indicates saturation: -ane (single bonds), -ene (double bonds), -yne (triple bonds)
Structural Isomerism
- Same molecular formula but different structural arrangements
- Five types: Chain, Position, Functional, Tautomerism, Metamerism
- Chain isomerism: Different carbon skeletons (n-butane vs isobutane)
Stereoisomerism
- Same molecular and structural formula but different spatial arrangement
- Three types: Conformational, Optical, Geometrical
- Conformational: Due to rotation around single bonds (staggered vs eclipsed)
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